Taming transport in InN : Indium Nitride and Related Alloys
Identifieur interne : 001407 ( Main/Repository ); précédent : 001406; suivant : 001408Taming transport in InN : Indium Nitride and Related Alloys
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Abstract
The large electron affinity of InN, close to 6 eV and the largest of any III-V semiconductor, creates a strong driving force for native donor formation, both in the bulk and at surfaces and interfaces. Moreover, all InN surfaces. regardless of crystal orientation or doping, have been observed to have a surface accumulation layer of electrons, which interferes with standard electrical measurements. For these reasons, until recently, it was uncertain whether or not compensation by donor defects would prevent "real" p-type activity (i.e., existence of sufficiently shallow acceptors and mobile holes). A coordinated experimental approach using a combination of electrical (Hall effect) and electrothermal (Seebeck coefficient) measurements will be described that allows definitive evaluation of carrier transport in InN. In Mg-doped InN films, the sensitivity of thermopower to bulk hole conduction, combined with modeling of the parallel conducting layers (surface/bulk/interface), enables quantitative measurement of the free hole concentration and mobility. In undoped (n-type) material, combined Hall and thermopower measurements, along with a considering of the scattering mechanisms, leads to a quantitative understanding of the crucial role of charged line defects in limiting electron transport.
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<author><name sortKey="Ager, Joel W Iii" uniqKey="Ager J">Joel W. Iii Ager</name>
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<author><name sortKey="Miller, Nate R" uniqKey="Miller N">Nate R. Miller</name>
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<title level="j" type="abbreviated">Phys. status solidi, A Appl. mater. sci. : (Print)</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Accumulation layers</term>
<term>Carrier mobility</term>
<term>Dislocations</term>
<term>Donor center</term>
<term>Doping</term>
<term>Hall effect</term>
<term>III-V semiconductors</term>
<term>Impurity density</term>
<term>Indium nitride</term>
<term>Inversion layers</term>
<term>Magnesium additions</term>
<term>Molecular beam epitaxy</term>
<term>Seebeck effect</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Dislocation</term>
<term>Addition magnésium</term>
<term>Concentration impureté</term>
<term>Dopage</term>
<term>Epitaxie jet moléculaire</term>
<term>Couche accumulation</term>
<term>Couche inversion</term>
<term>Centre donneur</term>
<term>Effet Hall</term>
<term>Effet Seebeck</term>
<term>Mobilité porteur charge</term>
<term>Nitrure d'indium</term>
<term>Semiconducteur III-V</term>
</keywords>
<keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Dopage</term>
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<front><div type="abstract" xml:lang="en">The large electron affinity of InN, close to 6 eV and the largest of any III-V semiconductor, creates a strong driving force for native donor formation, both in the bulk and at surfaces and interfaces. Moreover, all InN surfaces. regardless of crystal orientation or doping, have been observed to have a surface accumulation layer of electrons, which interferes with standard electrical measurements. For these reasons, until recently, it was uncertain whether or not compensation by donor defects would prevent "real" p-type activity (i.e., existence of sufficiently shallow acceptors and mobile holes). A coordinated experimental approach using a combination of electrical (Hall effect) and electrothermal (Seebeck coefficient) measurements will be described that allows definitive evaluation of carrier transport in InN. In Mg-doped InN films, the sensitivity of thermopower to bulk hole conduction, combined with modeling of the parallel conducting layers (surface/bulk/interface), enables quantitative measurement of the free hole concentration and mobility. In undoped (n-type) material, combined Hall and thermopower measurements, along with a considering of the scattering mechanisms, leads to a quantitative understanding of the crucial role of charged line defects in limiting electron transport.</div>
</front>
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<fA11 i1="01" i2="1"><s1>AGER (Joel W. III)</s1>
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<fA11 i1="02" i2="1"><s1>MILLER (Nate R.)</s1>
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<fA14 i1="01"><s1>Materials Sciences Division, Lawrence Berkeley National Lab.</s1>
<s2>Berkeley, CA 94720</s2>
<s3>USA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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<fA14 i1="02"><s1>Emcore, Albuquerque</s1>
<s2>NM 87123</s2>
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<fC01 i1="01" l="ENG"><s0>The large electron affinity of InN, close to 6 eV and the largest of any III-V semiconductor, creates a strong driving force for native donor formation, both in the bulk and at surfaces and interfaces. Moreover, all InN surfaces. regardless of crystal orientation or doping, have been observed to have a surface accumulation layer of electrons, which interferes with standard electrical measurements. For these reasons, until recently, it was uncertain whether or not compensation by donor defects would prevent "real" p-type activity (i.e., existence of sufficiently shallow acceptors and mobile holes). A coordinated experimental approach using a combination of electrical (Hall effect) and electrothermal (Seebeck coefficient) measurements will be described that allows definitive evaluation of carrier transport in InN. In Mg-doped InN films, the sensitivity of thermopower to bulk hole conduction, combined with modeling of the parallel conducting layers (surface/bulk/interface), enables quantitative measurement of the free hole concentration and mobility. In undoped (n-type) material, combined Hall and thermopower measurements, along with a considering of the scattering mechanisms, leads to a quantitative understanding of the crucial role of charged line defects in limiting electron transport.</s0>
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<fC02 i1="01" i2="3"><s0>001B70B20P</s0>
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<fC03 i1="01" i2="3" l="FRE"><s0>Dislocation</s0>
<s5>02</s5>
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<fC03 i1="01" i2="3" l="ENG"><s0>Dislocations</s0>
<s5>02</s5>
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<fC03 i1="02" i2="3" l="FRE"><s0>Addition magnésium</s0>
<s5>03</s5>
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<fC03 i1="02" i2="3" l="ENG"><s0>Magnesium additions</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Concentration impureté</s0>
<s5>04</s5>
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<fC03 i1="03" i2="X" l="ENG"><s0>Impurity density</s0>
<s5>04</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Concentración impureza</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Dopage</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Doping</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Doping</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Epitaxie jet moléculaire</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Molecular beam epitaxy</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Couche accumulation</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Accumulation layers</s0>
<s5>07</s5>
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<s5>08</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Inversion layers</s0>
<s5>08</s5>
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<fC03 i1="08" i2="X" l="FRE"><s0>Centre donneur</s0>
<s5>09</s5>
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<fC03 i1="08" i2="X" l="ENG"><s0>Donor center</s0>
<s5>09</s5>
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<fC03 i1="08" i2="X" l="SPA"><s0>Centro dador</s0>
<s5>09</s5>
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<fC03 i1="09" i2="3" l="FRE"><s0>Effet Hall</s0>
<s5>11</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG"><s0>Hall effect</s0>
<s5>11</s5>
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<fC03 i1="10" i2="3" l="FRE"><s0>Effet Seebeck</s0>
<s5>12</s5>
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<fC03 i1="10" i2="3" l="ENG"><s0>Seebeck effect</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>Mobilité porteur charge</s0>
<s5>13</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG"><s0>Carrier mobility</s0>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Nitrure d'indium</s0>
<s5>15</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Indium nitride</s0>
<s5>15</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Indio nitruro</s0>
<s5>15</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>Semiconducteur III-V</s0>
<s5>16</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG"><s0>III-V semiconductors</s0>
<s5>16</s5>
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<fN21><s1>023</s1>
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